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Aqueous zinc–manganese dioxide (Zn–MnO2) batteries show great promise for grid-scale energy storage but suffer from sluggish reaction kinetics and severe structural instability of the MnO2 cathode. Herein, a K+-pre-intercalated α-MnO2 cathode with oxygen defects (KMOd) is designed, guided by a new coupling engineer Journal of Materials Chemistry A HOT Papers
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